Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra

Wang，Heng1,2; Wang，Kun3; Xu，Yaping4; Wang，Wu5; Chen，Shaohua6; Hart，Matthew6; Wojtas，Lukasz7; Zhou，Li Peng8; Gan，Lin9; Yan，Xuzhou10; Li，Yiming7; Lee，Juhoon11; Ke，Xian Sheng11; Wang，Xu Qing12; Zhang，Chang Wei12; Zhou，Shasha9; Zhai，Tianyou9; Yang，Hai Bo12; Wang，Ming4; He，Jiaqing5; Sun，Qing Fu8; Xu，Bingqian13; Jiao，Yang6; Stang，Peter J.14; Sessler，Jonathan L.11; Li，Xiaopeng1,2

2021

10.1021/jacs.1c00625

Journal of the American Chemical Society   影响因子和分区

0002-7863

1520-5126

Parastichy, the spiral arrangement of plant organs, is an example of the long-range apparent order seen in biological systems. These ordered arrangements provide scientists with both an aesthetic challenge and a mathematical inspiration. Synthetic efforts to replicate the regularity of parastichy may allow for molecular-scale control over particle arrangement processes. Here we report the packing of a supramolecular truncated cuboctahedron (TCO) into double-helical (DH) nanowires on a graphite surface with a non-natural parastichy pattern ascribed to the symmetry of the TCOs and interactions between TCOs. Such a study is expected to advance our understanding of the design inputs needed to create complex, but precisely controlled, hierarchical materials. It is also one of the few reported helical packing structures based on Platonic or Archimedean solids since the discovery of the Boerdijk-Coxeter helix. As such, it may provide experimental support for studies of packing theory at the molecular level.

SCI ; EI

英语

NI期刊 ; NI论文

其他

U.S. National Science Foundation["CHE-1346572","DMR-1531283","ECCS-1609788","CHE-1807152"] ; Robert A. Welch Foundation[F-0018] ; U.S. Department of Energy (DOE) Office of Science[DE-AC02-06CH11357]

Chemistry

Chemistry, Multidisciplinary

WOS:000643591600033

AMER CHEMICAL SOC

20211910309465

Biological organs ; Self assembly ; Supramolecular chemistry

Biological Materials and Tissue Engineering:461.2 ; Nanotechnology:761 ; Physical Chemistry:801.4 ; Solid State Physics:933 ; Materials Science:951

2-s2.0-85105084083

Scopus

1.College of Chemistry and Environmental Engineering,Shenzhen University,Shenzhen,518060,China
2.Shenzhen University General Hospital,Shenzhen University Clinical Medical Academy,Shenzhen,518055,China
3.Departments of Physics and Astronomy and Chemistry,Mississippi State University,Mississippi State,39762,United States
4.State Key Laboratory of Supramolecular Structure and Materials,College of Chemistry,Jilin University,Changchun,130012,China
5.Department of Physics,Southern University of Science and Technology,Shenzhen,518055,China
6.School for Engineering of Matter,Transport and Energy,Arizona State University,Tempe,85287,United States
7.Department of Chemistry,University of South Florida,Tampa,33620,United States
8.State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,350002,China
9.State Key Laboratory of Material Processing and Die and Mould Technology,School of Materials Science and Engineering,Huazhong University of Science and Technology,Wuhan,430074,China
10.School of Chemistry and Chemical Engineering,Frontiers Science Center for Transformative Molecules,Shanghai Jiao Tong University,Shanghai,200240,China
11.Department of Chemistry,The University of Texas,Austin,78712,United States
12.Shanghai Key Laboratory of Green Chemistry and Chemical Processes,School of Chemistry and Molecular Engineering,East China Normal University,Shanghai,200062,China
13.College of Engineering and Nanoscale Science and Engineering Center,University of Georgia,Athens,30602,United States
14.Department of Chemistry,University of Utah,Salt Lake City,84112,United States

Wang，Heng,Wang，Kun,Xu，Yaping,et al. Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra[J]. Journal of the American Chemical Society,2021,143(15):5826-5835.

Wang，Heng.,Wang，Kun.,Xu，Yaping.,Wang，Wu.,Chen，Shaohua.,...&Li，Xiaopeng.(2021).Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra.Journal of the American Chemical Society,143(15),5826-5835.

Wang，Heng,et al."Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra".Journal of the American Chemical Society 143.15(2021):5826-5835.